At least four hours before you're ready to start cooking, season the chicken thighs with the salt, pepper and cayenne. Refrigerate for at least four hours.
When you're ready to begin cooking, preheat your oven to 275 degrees and heat the ½ cup of Carbonell Olive Oil over medium-high heat in a large pan. When the oil is nice and hot, add your chicken thighs and cook until browned - about five minutes.
Be careful when turning the chicken thighs because the olive oil might sputter a bit!